Polymeric concentrated electrolyte enables simultaneous stabilization of electrode/electrolyte interphases for quasi?solid?state lithium metal batteries
نویسندگان
چکیده
To achieve next-generation lithium metal batteries (LMBs) with desirable specific energy and reliability, the electrolyte shown simultaneously high reductive stability toward anode oxidative high-voltage cathode is of great importance. Here, we report for first time that high-concentration bis(fluorosulfonyl)imide (LiFSI) initiates ring-opening polymerization 1,3-dioxolane in presence ethylene carbonate ethylmethyl to produce in-situ a novel polymeric concentrated quasi-solid (poly-CQSE). The unique poly-CQSE 10 M LiFSI forms mixed-lithiophobic-conductive LiF-Li3N solid interphase on anode, F-rich conformal LiNi0.5Co0.2Mn0.3O2 (NCM523) simultaneously. As result, not only enables stable Li plating/stripping metallic at sound Coulombic efficiency 95.3% without dendrite growth, but also cycling Li||NCM523 quasi-solid-state LMB capacity retention 94% over 100 cycles.
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ژورنال
عنوان ژورنال: EcoMat
سال: 2023
ISSN: ['2567-3173']
DOI: https://doi.org/10.1002/eom2.12325